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Synthesis of High-Molecular-Weight Branched Polyethylene Using a Hybrid “Sandwich” Pyridine-Imine Ni(II) Catalyst

Most pyridine-imine Ni(II) and Pd(II) catalysts tend to yield low-molecular-weight polyethylene and ethylene-based copolymers in olefin insertion polymerization, as the unilateral axial steric structure of such complexes often cannot provide effective shielding of the metal center. In this study, we...

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Detalles Bibliográficos
Autores principales: Ge, You, Cai, Qi, Wang, Yuyin, Gao, Jiangang, Chi, Yue, Dai, Shengyu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9114440/
https://www.ncbi.nlm.nih.gov/pubmed/35601545
http://dx.doi.org/10.3389/fchem.2022.886888