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Gold-Aluminyl and Gold-Diarylboryl Complexes: Bonding and Reactivity with Carbon Dioxide

[Image: see text] The unconventional carbon dioxide insertion reaction of a gold-aluminyl [(t)Bu(3)PAuAl(NON)] complex has been recently shown to be related to the electron-sharing character of the Au–Al bond that acts as a nucleophile and stabilizes the insertion product through a radical-like beha...

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Detalles Bibliográficos
Autores principales: Sorbelli, Diego, Rossi, Elisa, Havenith, Remco W.A., Klein, Johannes E.M.N., Belpassi, Leonardo, Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9115750/
https://www.ncbi.nlm.nih.gov/pubmed/35512414
http://dx.doi.org/10.1021/acs.inorgchem.2c00174