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Gold-Aluminyl and Gold-Diarylboryl Complexes: Bonding and Reactivity with Carbon Dioxide
[Image: see text] The unconventional carbon dioxide insertion reaction of a gold-aluminyl [(t)Bu(3)PAuAl(NON)] complex has been recently shown to be related to the electron-sharing character of the Au–Al bond that acts as a nucleophile and stabilizes the insertion product through a radical-like beha...
Autores principales: | Sorbelli, Diego, Rossi, Elisa, Havenith, Remco W.A., Klein, Johannes E.M.N., Belpassi, Leonardo, Belanzoni, Paola |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9115750/ https://www.ncbi.nlm.nih.gov/pubmed/35512414 http://dx.doi.org/10.1021/acs.inorgchem.2c00174 |
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