Cargando…

Heme compound II models in chemoselectivity and disproportionation reactions

Heme compound II models bearing electron-deficient and -rich porphyrins, [Fe(IV)(O)(TPFPP)(Cl)](−) (1a) and [Fe(IV)(O)(TMP)(Cl)](−) (2a), respectively, are synthesized, spectroscopically characterized, and investigated in chemoselectivity and disproportionation reactions using cyclohexene as a mecha...

Descripción completa

Detalles Bibliográficos
Autores principales: Gupta, Ranjana, Li, Xiao-Xi, Lee, Youngseob, Seo, Mi Sook, Lee, Yong-Min, Yanagisawa, Sachiko, Kubo, Minoru, Sarangi, Ritimukta, Cho, Kyung-Bin, Fukuzumi, Shunichi, Nam, Wonwoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9116367/
https://www.ncbi.nlm.nih.gov/pubmed/35694346
http://dx.doi.org/10.1039/d2sc01232d