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Bulky and Stable Copper(I)-Phenanthroline Complex: Impact of Steric Strain and Symmetry on the Excited-State Properties

[Image: see text] The steric strain around copper(I) in typical [Cu(NN(R))(2)](+) complexes, where NN(R) is a diimine ligand substituted in α-positions of the nitrogen atoms by R, is known to strongly impact the excited-state properties. Generally speaking, the larger the R, the longer the emission...

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Detalles Bibliográficos
Autores principales: Gimeno, Lea, Phelan, Brian T., Sprague-Klein, Emily A., Roisnel, Thierry, Blart, Errol, Gourlaouen, Christophe, Chen, Lin X., Pellegrin, Yann
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9116384/
https://www.ncbi.nlm.nih.gov/pubmed/35507920
http://dx.doi.org/10.1021/acs.inorgchem.1c03901