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Bulky and Stable Copper(I)-Phenanthroline Complex: Impact of Steric Strain and Symmetry on the Excited-State Properties
[Image: see text] The steric strain around copper(I) in typical [Cu(NN(R))(2)](+) complexes, where NN(R) is a diimine ligand substituted in α-positions of the nitrogen atoms by R, is known to strongly impact the excited-state properties. Generally speaking, the larger the R, the longer the emission...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9116384/ https://www.ncbi.nlm.nih.gov/pubmed/35507920 http://dx.doi.org/10.1021/acs.inorgchem.1c03901 |