Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain

Pd catalysts are widely used in alkynol semi-hydrogenation. However, due to the existence of scaling relationships of adsorption energies between the key adsorbed species, the increase in conversion is frequently accompanied by side reactions, thereby reducing the selectivity to alkenols. We report...

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Detalles Bibliográficos
Autores principales: Yang, Yang, Zhu, Xiaojuan, Wang, Lili, Lang, Junyu, Yao, Guohua, Qin, Tian, Ren, Zhouhong, Chen, Liwei, Liu, Xi, Li, Wei, Wan, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9117217/
https://www.ncbi.nlm.nih.gov/pubmed/35585084
http://dx.doi.org/10.1038/s41467-022-30540-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9117217/
https://www.ncbi.nlm.nih.gov/pubmed/35585084
http://dx.doi.org/10.1038/s41467-022-30540-z

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