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Chemo- and regioselective benzylic C(sp(3))–H oxidation bridging the gap between hetero- and homogeneous copper catalysis

Selective C‒H functionalization in a pool of proximal C‒H bonds, predictably altering their innate reactivity is a daunting challenge. We disclose here, an expedient synthesis of privileged seven-membered lactones, dibenzo[c,e]oxepin-5(7H)-one through a highly chemoselective benzylic C(sp(3))‒H acti...

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Detalles Bibliográficos
Autores principales: Nandi, Shantanu, Mondal, Shuvam, Jana, Ranjan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9118691/
https://www.ncbi.nlm.nih.gov/pubmed/35602936
http://dx.doi.org/10.1016/j.isci.2022.104341