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Chemo- and regioselective benzylic C(sp(3))–H oxidation bridging the gap between hetero- and homogeneous copper catalysis
Selective C‒H functionalization in a pool of proximal C‒H bonds, predictably altering their innate reactivity is a daunting challenge. We disclose here, an expedient synthesis of privileged seven-membered lactones, dibenzo[c,e]oxepin-5(7H)-one through a highly chemoselective benzylic C(sp(3))‒H acti...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9118691/ https://www.ncbi.nlm.nih.gov/pubmed/35602936 http://dx.doi.org/10.1016/j.isci.2022.104341 |