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Intermolecular 2+2 imine-olefin photocycloadditions enabled by Cu(I)-alkene MLCT

2 + 2 Photocycloadditions are idealized, convergent construction approaches of 4-membered heterocyclic rings, including azetidines. However, methods of direct excitation are limited by the unfavorable photophysical properties of imines and electronically unbiased alkenes. Here, we report copper-cata...

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Detalles Bibliográficos
Autores principales: Flores, Daniel M., Neville, Michael L., Schmidt, Valerie A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9120151/
https://www.ncbi.nlm.nih.gov/pubmed/35589714
http://dx.doi.org/10.1038/s41467-022-30393-6