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Real-Time High-Sensitivity Reaction Monitoring of Important Nitrogen-Cycle Synthons by (15)N Hyperpolarized Nuclear Magnetic Resonance
[Image: see text] Here, we show how signal amplification by reversible exchange hyperpolarization of a range of (15)N-containing synthons can be used to enable studies of their reactivity by (15)N nuclear magnetic resonance (NO(2)(–) (28% polarization), ND(3) (3%), PhCH(2)NH(2) (5%), NaN(3) (3%), an...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9121385/ https://www.ncbi.nlm.nih.gov/pubmed/35508182 http://dx.doi.org/10.1021/jacs.2c02619 |