Real-Time High-Sensitivity Reaction Monitoring of Important Nitrogen-Cycle Synthons by (15)N Hyperpolarized Nuclear Magnetic Resonance

[Image: see text] Here, we show how signal amplification by reversible exchange hyperpolarization of a range of (15)N-containing synthons can be used to enable studies of their reactivity by (15)N nuclear magnetic resonance (NO(2)(–) (28% polarization), ND(3) (3%), PhCH(2)NH(2) (5%), NaN(3) (3%), an...

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Detalles Bibliográficos
Autores principales: Rayner, Peter J., Fekete, Marianna, Gater, Callum A., Ahwal, Fadi, Turner, Norman, Kennerley, Aneurin J., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9121385/
https://www.ncbi.nlm.nih.gov/pubmed/35508182
http://dx.doi.org/10.1021/jacs.2c02619

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