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Mechanism-Dependent Selectivity: Fluorocyclization of Unsaturated Carboxylic Acids or Alcohols by Hypervalent Iodine

To understand the unprecedented difference between 6-endo and 5-exo selectivity in hypervalent iodine (III) promoted fluorocyclization of unsaturated carboxylic acids or alcohols by difluoroiodotoluene, density functional theory (DFT) studies have been performed to systematically compare both the pr...

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Detalles Bibliográficos
Autores principales: Su, Jiaqi, Shu, Siwei, Li, Yinwu, Chen, Yong, Dong, Jinxiang, Liu, Yan, Fang, Yanxiong, Ke, Zhuofeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9127131/
https://www.ncbi.nlm.nih.gov/pubmed/35620652
http://dx.doi.org/10.3389/fchem.2022.897828