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Ring walking as a regioselectivity control element in Pd-catalyzed C-N cross-coupling

Ring walking is an important mechanistic phenomenon leveraged in many catalytic C-C bond forming reactions. However, ring walking has been scarcely studied under Buchwald-Hartwig amination conditions despite the importance of such transformations. An in-depth mechanistic study of the Buchwald-Hartwi...

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Detalles Bibliográficos
Autores principales: Deem, Madeleine C., Derasp, Joshua S., Malig, Thomas C., Legard, Kea, Berlinguette, Curtis P., Hein, Jason E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9130136/
https://www.ncbi.nlm.nih.gov/pubmed/35610226
http://dx.doi.org/10.1038/s41467-022-30255-1