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N-Centered Tripodal Phosphine Re(V) and Tc(V) Oxo Complexes: Revisiting a [3 + 2] Mixed-Ligand Approach

[Image: see text] N-Triphos derivatives (NP(3)(R), R = alkyl, aryl) and asymmetric variants (NP(2)(R)X(R′), R′ = alkyl, aryl, X = OH, NR(2), NRR′) are an underexplored class of tuneable, tripodal ligands in relation to the coordination chemistry of Re and Tc for biomedical applications. Mixed-ligand...

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Detalles Bibliográficos
Autores principales: Cooper, Saul M., White, Andrew J. P., Eykyn, Thomas R., Ma, Michelle T., Miller, Philip W., Long, Nicholas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9131457/
https://www.ncbi.nlm.nih.gov/pubmed/35544683
http://dx.doi.org/10.1021/acs.inorgchem.2c00693