Antisymmetric Spin Exchange in a μ-1,2-Peroxodicopper(II) Complex with an Orthogonal Cu–O–O–Cu Arrangement and S = 1 Spin Ground State Characterized by THz-EPR

[Image: see text] A unique type of Cu(2)/O(2) adduct with orthogonal (close to 90°) Cu–O–O–Cu arrangement has been proposed for initial stages of O(2) binding at biological type III dicopper sites, and targeted ligand design has now allowed us to emulate such an adduct in a pyrazolate-based μ-η(1):η...

Descripción completa

Detalles Bibliográficos
Autores principales: Lohmiller, Thomas, Spyra, Can-Jerome, Dechert, Sebastian, Demeshko, Serhiy, Bill, Eckhard, Schnegg, Alexander, Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9131480/
https://www.ncbi.nlm.nih.gov/pubmed/35647586
http://dx.doi.org/10.1021/jacsau.2c00139

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9131480/
https://www.ncbi.nlm.nih.gov/pubmed/35647586
http://dx.doi.org/10.1021/jacsau.2c00139

Ejemplares similares