Cargando…
Antisymmetric Spin Exchange in a μ-1,2-Peroxodicopper(II) Complex with an Orthogonal Cu–O–O–Cu Arrangement and S = 1 Spin Ground State Characterized by THz-EPR
[Image: see text] A unique type of Cu(2)/O(2) adduct with orthogonal (close to 90°) Cu–O–O–Cu arrangement has been proposed for initial stages of O(2) binding at biological type III dicopper sites, and targeted ligand design has now allowed us to emulate such an adduct in a pyrazolate-based μ-η(1):η...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9131480/ https://www.ncbi.nlm.nih.gov/pubmed/35647586 http://dx.doi.org/10.1021/jacsau.2c00139 |