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Diastereoselective and enantioselective photoredox pinacol coupling promoted by titanium complexes with a red-absorbing organic dye

The pinacol coupling reaction, a reductive coupling of carbonyl compounds that proceeds through the formation of ketyl radicals in the presence of an electron donor, affords the corresponding 1,2-diols in one single step. The photoredox version of this transformation has been accomplished using diff...

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Detalles Bibliográficos
Autores principales: Calogero, Francesco, Magagnano, Giandomenico, Potenti, Simone, Pasca, Francesco, Fermi, Andrea, Gualandi, Andrea, Ceroni, Paola, Bergamini, Giacomo, Cozzi, Pier Giorgio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9132033/
https://www.ncbi.nlm.nih.gov/pubmed/35685797
http://dx.doi.org/10.1039/d2sc00800a