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Ligand-promoted palladium-catalyzed β-methylene C–H arylation of primary aldehydes

The transient directing group (TDG) strategy allowed long awaited access to the direct β-C(sp(3))–H functionalization of unmasked aliphatic aldehydes via palladium catalysis. However, the current techniques are restricted to terminal methyl functionalization, limiting their structural scopes and app...

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Detalles Bibliográficos
Autores principales: Yang, Ke, Li, Zhi, Liu, Chong, Li, Yunjian, Hu, Qingyue, Elsaid, Mazen, Li, Bijin, Das, Jayabrata, Dang, Yanfeng, Maiti, Debabrata, Ge, Haibo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9132077/
https://www.ncbi.nlm.nih.gov/pubmed/35685787
http://dx.doi.org/10.1039/d2sc01677j