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Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides

The widespread use of phosphine ligand libraries is frequently hampered by the challenges associated with their modular preparation. Here, we report a protocol that appends arenes to arylphosphines to access a series of biaryl monophosphines via rhodium-catalyzed P(III)-directed ortho C–H activation...

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Detalles Bibliográficos
Autores principales: Wang, Dingyi, Li, Mingjie, Shuang, Chengdong, Liang, Yong, Zhao, Yue, Wang, Minyan, Shi, Zhuangzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9132997/
https://www.ncbi.nlm.nih.gov/pubmed/35614077
http://dx.doi.org/10.1038/s41467-022-30697-7