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Ni-catalyzed hydroarylation of alkynes with unactivated β-C(sp(2))−H bonds

Hydroarylation of alkynes with unactivated C(sp(2))−H bonds via chelated C−H metalation mainly occurs at γ-position to the coordinating atom of directing groups via stable 5-membered metallacycles, while β-C(sp(2))−H bond-involved hydroarylation has been a formidable challenge. Herein, we used a pho...

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Detalles Bibliográficos
Autores principales: Qi, Shao-Long, Liu, Yu-Peng, Li, Yi, Luan, Yu-Xin, Ye, Mengchun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9135730/
https://www.ncbi.nlm.nih.gov/pubmed/35618702
http://dx.doi.org/10.1038/s41467-022-30367-8