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Ni-catalyzed hydroarylation of alkynes with unactivated β-C(sp(2))−H bonds
Hydroarylation of alkynes with unactivated C(sp(2))−H bonds via chelated C−H metalation mainly occurs at γ-position to the coordinating atom of directing groups via stable 5-membered metallacycles, while β-C(sp(2))−H bond-involved hydroarylation has been a formidable challenge. Herein, we used a pho...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9135730/ https://www.ncbi.nlm.nih.gov/pubmed/35618702 http://dx.doi.org/10.1038/s41467-022-30367-8 |