Structural Snapshots in Reversible Phosphinidene Transfer: Synthetic, Structural, and Reaction Chemistry of a Sn=P Double Bond

[Image: see text] The reaction of amido-substituted stannylenes with phospha-Wittig reagents (Me(3)PPR) results in release of hexamethyldisilazane and tethering of the resulting −CH(2)PMe(2)PR fragment to the tin center to give P-donor stabilized stannylenes featuring four-membered Sn,C,P,P heterocy...

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Detalles Bibliográficos
Autores principales: Fischer, Malte, Roy, Matthew M. D., Wales, Lewis L., Ellwanger, Mathias A., Heilmann, Andreas, Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9136930/
https://www.ncbi.nlm.nih.gov/pubmed/35536684
http://dx.doi.org/10.1021/jacs.2c03302

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9136930/
https://www.ncbi.nlm.nih.gov/pubmed/35536684
http://dx.doi.org/10.1021/jacs.2c03302

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