Overcoming O–H Insertion to Para-Selective C–H Functionalization of Free Phenols: Rh(II)/Xantphos Catalyzed Geminal Difunctionalization of Diazo Compounds

[Image: see text] Para-selective C–H functionalization of free phenols by metal carbenoids is rather challenging due to the generally more favorable competing O–H insertion. Herein, with the use of the combination of Rh(II) and a Xantphos ligand as the catalyst, a novel multicomponent reaction of fr...

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Detalles Bibliográficos
Autores principales: Yang, Yang, Lu, Bin, Xu, Guiqing, Wang, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9136979/
https://www.ncbi.nlm.nih.gov/pubmed/35647279
http://dx.doi.org/10.1021/acscentsci.2c00004

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9136979/
https://www.ncbi.nlm.nih.gov/pubmed/35647279
http://dx.doi.org/10.1021/acscentsci.2c00004

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