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Overcoming O–H Insertion to Para-Selective C–H Functionalization of Free Phenols: Rh(II)/Xantphos Catalyzed Geminal Difunctionalization of Diazo Compounds
[Image: see text] Para-selective C–H functionalization of free phenols by metal carbenoids is rather challenging due to the generally more favorable competing O–H insertion. Herein, with the use of the combination of Rh(II) and a Xantphos ligand as the catalyst, a novel multicomponent reaction of fr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9136979/ https://www.ncbi.nlm.nih.gov/pubmed/35647279 http://dx.doi.org/10.1021/acscentsci.2c00004 |