Generation and Reactions of ε-Carbonyl Cations via Group 13 Catalysis

The generation of ε-carbonyl cations and their reactions with nucleophiles is accomplished readily without transition metal cation stabilization, using the ε-bromide dienoate or dienone starting materials and GaCl(3) or InCl(3) catalysis. Arene nucleophiles are somewhat more straightforward than all...

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Detalles Bibliográficos
Autores principales: Penner, Page M., Green, James R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9146154/
https://www.ncbi.nlm.nih.gov/pubmed/35630554
http://dx.doi.org/10.3390/molecules27103078

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9146154/
https://www.ncbi.nlm.nih.gov/pubmed/35630554
http://dx.doi.org/10.3390/molecules27103078

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