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Generation and Reactions of ε-Carbonyl Cations via Group 13 Catalysis
The generation of ε-carbonyl cations and their reactions with nucleophiles is accomplished readily without transition metal cation stabilization, using the ε-bromide dienoate or dienone starting materials and GaCl(3) or InCl(3) catalysis. Arene nucleophiles are somewhat more straightforward than all...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9146154/ https://www.ncbi.nlm.nih.gov/pubmed/35630554 http://dx.doi.org/10.3390/molecules27103078 |