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Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo(2)LiH(2), Mo(2)Li(2)H(4), and Mo(6)Li(9)H(18) Clusters

[Image: see text] The reactions of LiAlH(4) as the source of LiH with complexes that contain (H)Mo≣Mo and (H)Mo≣Mo(H) cores stabilized by the coordination of bulky Ad(Dipp2) ligands result in the respective coordination of one and two molecules of (thf)LiH, with the generation of complexes exhibitin...

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Detalles Bibliográficos
Autores principales: Perez-Jimenez, Marina, Curado, Natalia, Maya, Celia, Campos, Jesus, Jover, Jesus, Alvarez, Santiago, Carmona, Ernesto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9157502/
https://www.ncbi.nlm.nih.gov/pubmed/33755447
http://dx.doi.org/10.1021/jacs.1c01602