Dynamic kinetic resolution of transient hemiketals: a strategy for the desymmetrisation of prochiral oxetanols

Identification of an electron poor trifluoroacetophenone allows the formation of uniquely stable hemiketals from prochiral oxetanols. When exposed to a cobalt(ii) catalyst, efficient ring-opening to densely functionalized dioxolanes is observed. Mechanistic studies suggest an unprecedented redox pro...

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Detalles Bibliográficos
Autores principales: Sandvoß, Alexander, Maag, Henning, Daniliuc, Constantin G., Schollmeyer, Dieter, Wahl, Johannes M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9159106/
https://www.ncbi.nlm.nih.gov/pubmed/35733901
http://dx.doi.org/10.1039/d2sc01547a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9159106/
https://www.ncbi.nlm.nih.gov/pubmed/35733901
http://dx.doi.org/10.1039/d2sc01547a

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