Organobase-catalyzed 1,1-diborylation of terminal alkynes under metal-free conditions

An organobase-catalyzed 1,1-diborylation of terminal alkynes from propargylic derivatives with bis(2,4-dimethylpentane-2,4-glycolato)diboron (B(2)oct(2)) is first reported, regioselectively providing 1,1-diborylalkene products with high efficiency. The catalytic pathway is well postulated on the bas...

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Detalles Bibliográficos
Autores principales: Li, Junchen, An, Min, Gao, Zhenhua, Guo, Yongbiao, Liu, Haibo, Zhao, Peichao, Bi, Xiaojing, Shi, Enxue, Xiao, Junhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9159348/
https://www.ncbi.nlm.nih.gov/pubmed/35747526
http://dx.doi.org/10.1039/d2ra02638d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9159348/
https://www.ncbi.nlm.nih.gov/pubmed/35747526
http://dx.doi.org/10.1039/d2ra02638d

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