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1,4-Aryl migration in ketene-derived enolates by a polar-radical-crossover cascade
The arylation of carboxylic acid derivatives via Smiles rearrangement has gained great interest in recent years. Both radical and ionic approaches, as well as radical-polar crossover concepts, have been developed. In contrast, a reversed polar-radical crossover approach remains underexplored. Here w...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9163183/ https://www.ncbi.nlm.nih.gov/pubmed/35655065 http://dx.doi.org/10.1038/s41467-022-30817-3 |