Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges

Treatment of [U(IV)(N(3))(Tren(TIPS))] (1, Tren(TIPS) = {N(CH(2)CH(2)NSiPr(i)(3))(3)}(3−)) with excess Li resulted in the isolation of [{U(IV)(μ-NLi(2))(Tren(TIPS))}(2)] (2), which exhibits a diuranium(iv) ‘diamond-core’ dinitride motif. Over-reduction of 1 produces [U(III)(Tren(TIPS))] (3), and tog...

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Detalles Bibliográficos
Autores principales: King, David M., Atkinson, Benjamin E., Chatelain, Lucile, Gregson, Matthew, Seed, John A., Wooles, Ashley J., Kaltsoyannis, Nikolas, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9171730/
https://www.ncbi.nlm.nih.gov/pubmed/35622422
http://dx.doi.org/10.1039/d2dt00998f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9171730/
https://www.ncbi.nlm.nih.gov/pubmed/35622422
http://dx.doi.org/10.1039/d2dt00998f

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