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Factors Governing Reactivity and Selectivity in Hydrogen Atom Transfer from C(sp(3))–H Bonds of Nitrogen-Containing Heterocycles to the Cumyloxyl Radical
[Image: see text] A kinetic study of the hydrogen atom transfer (HAT) reactions from nitrogen-containing heterocycles (secondary and tertiary lactams, 2-imidazolidinones, 2-oxazolidinones, and succinimides) to the cumyloxyl radical has been carried out employing laser flash photolysis with ns time r...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9171822/ https://www.ncbi.nlm.nih.gov/pubmed/35609878 http://dx.doi.org/10.1021/acs.joc.2c00955 |