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Factors Governing Reactivity and Selectivity in Hydrogen Atom Transfer from C(sp(3))–H Bonds of Nitrogen-Containing Heterocycles to the Cumyloxyl Radical

[Image: see text] A kinetic study of the hydrogen atom transfer (HAT) reactions from nitrogen-containing heterocycles (secondary and tertiary lactams, 2-imidazolidinones, 2-oxazolidinones, and succinimides) to the cumyloxyl radical has been carried out employing laser flash photolysis with ns time r...

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Detalles Bibliográficos
Autores principales:	Galeotti, Marco, Trasatti, Chiara, Sisti, Sergio, Salamone, Michela, Bietti, Massimo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9171822/ https://www.ncbi.nlm.nih.gov/pubmed/35609878 http://dx.doi.org/10.1021/acs.joc.2c00955

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