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Orbital analysis of bonding in diarylhalonium salts and relevance to periodic trends in structure and reactivity

Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field of organic synthesis. The three center, four electron (3c–4e) bond is a center piece of their reactivity, but structural variation among the diarylhaloniums, and in comparison with other λ(3)-iodanes, indicates...

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Detalles Bibliográficos
Autores principales: Karandikar, Shubhendu S., Bhattacharjee, Avik, Metze, Bryan E., Javaly, Nicole, Valente, Edward J., McCormick, Theresa M., Stuart, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9172531/
https://www.ncbi.nlm.nih.gov/pubmed/35756513
http://dx.doi.org/10.1039/d2sc02332f