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Orbital analysis of bonding in diarylhalonium salts and relevance to periodic trends in structure and reactivity
Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field of organic synthesis. The three center, four electron (3c–4e) bond is a center piece of their reactivity, but structural variation among the diarylhaloniums, and in comparison with other λ(3)-iodanes, indicates...
Autores principales: | Karandikar, Shubhendu S., Bhattacharjee, Avik, Metze, Bryan E., Javaly, Nicole, Valente, Edward J., McCormick, Theresa M., Stuart, David R. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9172531/ https://www.ncbi.nlm.nih.gov/pubmed/35756513 http://dx.doi.org/10.1039/d2sc02332f |
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