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Magnesium-stabilised transition metal formyl complexes: structures, bonding, and ethenediolate formation

Herein we report the first comprehensive series of crystallographically characterised transition metal formyl complexes. In these complexes, the formyl ligand is trapped as part of a chelating structure between a transition metal (Cr, Mn, Fe, Co, Rh, W, and Ir) and a magnesium (Mg) cation. Calculati...

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Detalles Bibliográficos
Autores principales: Parr, Joseph M., White, Andrew J. P., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9172563/
https://www.ncbi.nlm.nih.gov/pubmed/35756511
http://dx.doi.org/10.1039/d2sc02063g