Direct C–H amination reactions of arenes with N-hydroxyphthalimides catalyzed by cuprous bromide

An efficient Cu-catalyzed strategy for the direct C–H amination of arenes in high yields using N-hydroxyphthalimide as the amidyl radical precursor under air is reported. A possible mechanism is proposed that proceeds via a radical reaction in the presence of CuBr and triethyl phosphite.

Detalles Bibliográficos
Autores principales: Zhang, Dongming, Lv, Bin, Gao, Pan, Jia, Xiaodong, Yuan, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9174840/
https://www.ncbi.nlm.nih.gov/pubmed/35706994
http://dx.doi.org/10.3762/bjoc.18.65

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9174840/
https://www.ncbi.nlm.nih.gov/pubmed/35706994
http://dx.doi.org/10.3762/bjoc.18.65

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