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Molecule-like and lattice vibrations in metal clusters

We report distinct molecule-like and lattice (breathing) vibrational signatures of atomically precise, ligand-protected metal clusters using low-temperature Raman spectroscopy. Our measurements provide fingerprint Raman spectra of a series of noble metal clusters, namely, Au(25)(SR)(18), Ag(25)(SR)(...

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Detalles Bibliográficos
Autores principales: Ramankutty, Krishnadas Kumaranchira, Yang, Huayan, Baghdasaryan, Ani, Teyssier, Jeremie, Nicu, Valentin Paul, Buergi, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9176185/
https://www.ncbi.nlm.nih.gov/pubmed/35616625
http://dx.doi.org/10.1039/d1cp04708f