Assembly of a Dihydrideborate and Two Aryl Nitriles to Form a C,N,N′-Pincer Ligand Coordinated to Osmium

[Image: see text] The C,N,N′-donor aryl-diimineborate pincer ligand of the complexes OsH(2){κ(3)-C,N,N-[C(6)H(3)RCH=NB(cat)N=CHC(6)H(4)R]}(P(i)Pr(3))(2) (R = H, Me) has been generated in a one-pot procedure, by the reaction of the hexahydride OsH(6)(P(i)Pr(3))(2) with catecholborane (catBH) and two...

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Detalles Bibliográficos
Autores principales: Babón, Juan C., Esteruelas, Miguel A., Fernández, Israel, López, Ana M., Oñate, Enrique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180356/
https://www.ncbi.nlm.nih.gov/pubmed/35694319
http://dx.doi.org/10.1021/acs.organomet.0c00690

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180356/
https://www.ncbi.nlm.nih.gov/pubmed/35694319
http://dx.doi.org/10.1021/acs.organomet.0c00690

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