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Assembly of a Dihydrideborate and Two Aryl Nitriles to Form a C,N,N′-Pincer Ligand Coordinated to Osmium
[Image: see text] The C,N,N′-donor aryl-diimineborate pincer ligand of the complexes OsH(2){κ(3)-C,N,N-[C(6)H(3)RCH=NB(cat)N=CHC(6)H(4)R]}(P(i)Pr(3))(2) (R = H, Me) has been generated in a one-pot procedure, by the reaction of the hexahydride OsH(6)(P(i)Pr(3))(2) with catecholborane (catBH) and two...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180356/ https://www.ncbi.nlm.nih.gov/pubmed/35694319 http://dx.doi.org/10.1021/acs.organomet.0c00690 |