Repercussion of a 1,3-Hydrogen Shift in a Hydride-Osmium-Allenylidene Complex

[Image: see text] An unusual 1,3-hydrogen shift from the metal center to the C(β) atom of the C(3)-chain of the allenylidene ligand in a hydride-osmium(II)-allenylidene complex is the beginning of several interesting transformations in the cumulene. The hydride-osmium(II)-allenylidene complex was pr...

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Detalles Bibliográficos
Autores principales: Esteruelas, Miguel A., Oñate, Enrique, Paz, Sonia, Vélez, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180373/
https://www.ncbi.nlm.nih.gov/pubmed/35693112
http://dx.doi.org/10.1021/acs.organomet.1c00176

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180373/
https://www.ncbi.nlm.nih.gov/pubmed/35693112
http://dx.doi.org/10.1021/acs.organomet.1c00176

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