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Repercussion of a 1,3-Hydrogen Shift in a Hydride-Osmium-Allenylidene Complex
[Image: see text] An unusual 1,3-hydrogen shift from the metal center to the C(β) atom of the C(3)-chain of the allenylidene ligand in a hydride-osmium(II)-allenylidene complex is the beginning of several interesting transformations in the cumulene. The hydride-osmium(II)-allenylidene complex was pr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180373/ https://www.ncbi.nlm.nih.gov/pubmed/35693112 http://dx.doi.org/10.1021/acs.organomet.1c00176 |