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Preparation and Degradation of Rhodium and Iridium Diolefin Catalysts for the Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols

[Image: see text] Rhodium and iridium diolefin catalysts for the acceptorless and base-free dehydrogenation of secondary alcohols have been prepared, and their degradation has been investigated, during the study of the reactivity of the dimers [M(μ-Cl)(η(4)-C(8)H(12))](2) (M = Rh (1), Ir (2)) and [M...

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Detalles Bibliográficos
Autores principales: Buil, María L., Collado, Alba, Esteruelas, Miguel A., Gómez-Gallego, Mar, Izquierdo, Susana, Nicasio, Antonio I., Oñate, Enrique, Sierra, Miguel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9180741/
https://www.ncbi.nlm.nih.gov/pubmed/35692372
http://dx.doi.org/10.1021/acs.organomet.1c00068