Meso- and Rac-[bis(3-phenyl-6-tert-butylinden-1-yl)dimethylsilyl]zirconium Dichloride: Precatalysts for the Production of Differentiated Polyethylene Products with Enhanced Properties

Ansa-zirconocene complexes are widely employed as precatalysts for olefin polymerization. Their synthesis generally leads to mixtures of their rac and meso isomers, whose separation is often problematic. In this contribution, we report on the synthesis of a novel silyl-bridged bis(indenyl)-based met...

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Detalles Bibliográficos
Autores principales: Giffin, Kaitie A., Cirriez, Virginie, Santoro, Orlando, Welle, Alexandre, Kirillov, Evgueni, Carpentier, Jean-François
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9183169/
https://www.ncbi.nlm.nih.gov/pubmed/35683890
http://dx.doi.org/10.3390/polym14112217

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9183169/
https://www.ncbi.nlm.nih.gov/pubmed/35683890
http://dx.doi.org/10.3390/polym14112217

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