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Collective Synthesis of Illudalane Sesquiterpenes via Cascade Inverse Electron Demand (4 + 2) Cycloadditions of Thiophene S,S-Dioxides

[Image: see text] Thiophene S,S-dioxides are underutilized tools for the de novo construction of benzene rings in organic synthesis. We report a collective synthesis of nine illudalane sesquiterpenes using bicyclic thiophene S,S-dioxides as generalized precursors to the indane core of the natural pr...

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Detalles Bibliográficos
Autores principales: Park, Kun Ho Kenny, Frank, Nils, Duarte, Fernanda, Anderson, Edward A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9185749/
https://www.ncbi.nlm.nih.gov/pubmed/35609003
http://dx.doi.org/10.1021/jacs.2c03304