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N-Aminopyridinium reagents as traceless activating groups in the synthesis of N-Aryl aziridines

N-functionalized aziridines, which are both useful intermediates and important synthetic targets, can be envisioned as arising from the addition of nitrenes (i.e., NR fragments) to olefinic substrates. The exceptional reactivity of most nitrenes, in particular with respect to unimolecular decomposit...

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Detalles Bibliográficos
Autores principales: Tan, Hao, Samanta, Samya, Maity, Asim, Roychowdhury, Pritam, Powers, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9187731/
https://www.ncbi.nlm.nih.gov/pubmed/35689000
http://dx.doi.org/10.1038/s41467-022-31032-w