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Electron Affinities of Ligated Icosahedral M(13) Superatoms Revisited by Gas-Phase Anion Photoelectron Spectroscopy

[Image: see text] The electron binding energies of the ligand-protected gold/silver-based cluster anions, [Au(25)(SR)(18)](−), [XAg(24)(SR′)(18)](2–) (X = Ag(+), Au(+), Pd(0), or Pt(0)), and [PdAu(24)(C≡CR″)(18)](2–) having icosahedral M(13) superatomic cores, were reexamined by gas-phase photoelect...

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Detalles Bibliográficos
Autores principales: Ito, Shun, Tasaka, Yuriko, Nakamura, Katsunosuke, Fujiwara, Yuki, Hirata, Keisuke, Koyasu, Kiichirou, Tsukuda, Tatsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9190706/
https://www.ncbi.nlm.nih.gov/pubmed/35652790
http://dx.doi.org/10.1021/acs.jpclett.2c01284