Radical 1,2,3-tricarbofunctionalization of α-vinyl-β-ketoesters enabled by a carbon shift from an all-carbon quaternary center

Herein, we report an intermolecular, radical 1,2,3-tricarbofunctionalization of α-vinyl-β-ketoesters to achieve the goal of building molecular complexity via the one-pot multifunctionalization of alkenes. This reaction allows the expansion of the carbon ring by a carbon shift from an all-carbon quat...

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Detalles Bibliográficos
Autores principales: Zhang, Qi, Chiou, Mong-Feng, Ye, Changqing, Yuan, Xiaobin, Li, Yajun, Bao, Hongli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200052/
https://www.ncbi.nlm.nih.gov/pubmed/35774175
http://dx.doi.org/10.1039/d2sc00902a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200052/
https://www.ncbi.nlm.nih.gov/pubmed/35774175
http://dx.doi.org/10.1039/d2sc00902a

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