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Radical 1,2,3-tricarbofunctionalization of α-vinyl-β-ketoesters enabled by a carbon shift from an all-carbon quaternary center
Herein, we report an intermolecular, radical 1,2,3-tricarbofunctionalization of α-vinyl-β-ketoesters to achieve the goal of building molecular complexity via the one-pot multifunctionalization of alkenes. This reaction allows the expansion of the carbon ring by a carbon shift from an all-carbon quat...
Autores principales: | Zhang, Qi, Chiou, Mong-Feng, Ye, Changqing, Yuan, Xiaobin, Li, Yajun, Bao, Hongli |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200052/ https://www.ncbi.nlm.nih.gov/pubmed/35774175 http://dx.doi.org/10.1039/d2sc00902a |
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