Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes

We present the use of gold sensitizers [Au(SIPr)(Cbz)] (PhotAu 1) and [Au(IPr)(Cbz)] (PhotAu 2) as attractive alternatives to state-of-the-art iridium-based systems. These novel photocatalysts are deployed in [2 + 2] cycloadditions of diallyl ethers and N-tosylamides. The reactions proceed in short...

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Detalles Bibliográficos
Autores principales: Martynova, Ekaterina A., Voloshkin, Vladislav A., Guillet, Sébastien G., Bru, Francis, Beliš, Marek, Van Hecke, Kristof, Cazin, Catherine S. J., Nolan, Steven P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200118/
https://www.ncbi.nlm.nih.gov/pubmed/35774168
http://dx.doi.org/10.1039/d2sc00864e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200118/
https://www.ncbi.nlm.nih.gov/pubmed/35774168
http://dx.doi.org/10.1039/d2sc00864e

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