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Asymmetric Assembly of Chiral Lanthanide(III) Tetranuclear Cluster Complexes Using Achiral Mixed Ligands: Single-molecule Magnet Behavior and Magnetic Entropy Change
[Image: see text] It is challenging to use achiral ligands to spontaneously construct chiral molecular magnets. In this work, two new Ln(4) cluster complexes based on N,N′-(1,3-propanediyl)bis[N-[1,1-bis(hydroxymethyl)-2-hydroxyethyl]amine] (H(6)L) have been assembled, which are crystallized in a ch...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9202287/ https://www.ncbi.nlm.nih.gov/pubmed/35721968 http://dx.doi.org/10.1021/acsomega.2c02155 |